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, antifouling, and permeation properties of polysulfone ultrafiltration membrane: thermodynamic and formation

《化学科学与工程前沿(英文)》 2023年 第17卷 第10期   页码 1484-1502 doi: 10.1007/s11705-023-2331-y

摘要: Various hydrophilic poly(ethylene-co-vinyl alcohol) (EVOH) were used herein to precisely control the structure and hydrodynamic properties of polysulfone (PSF) membranes. Particularly, to prepare pristine PSF and PSF/EVOH blends with increasing vinyl alcohol (VOH: 73%, 68%, 56%), the non-solvent-induced phase separation (NIPS) technique was used. Polyethylene glycol was used as a compatibilizer and as a porogen in N,N-dimethylacetamide. Rheological and ultrasonic separation kinetic measurements were also carried out to develop an ultrafiltration membrane mechanism. The extracted membrane properties and filtration capabilities were systematically compared to the proposed mechanism. Accordingly, the addition of EVOH led to an increase in the rheology of the dopes. The resulting membranes exhibited a microporous structure, while the finger-like structures became more evident with increasing VOH content. The PSF/EVOH behavior was changed from immediate to delayed segregation due to a change in the hydrodynamic kinetics. Interestingly, the PSF/EVOH32 membranes showed high hydrophilicity and achieved a pure water permeability of 264 L·m–2·h–1·bar–1, which was higher than that of pure PSF membranes (171 L·m–2·h–1·bar–1). In addition, PSF/EVOH32 rejected bovine serum albumin at a high rate (> 90%) and achieved a significant restoration of permeability. Finally, from the thermodynamic and hydrodynamic results, valuable insights into the selection of hydrophilic copolymers were provided to tailor the membrane structure while improving both the permeability and antifouling performance.

关键词: polysulfone     blend modification     ultrafiltration membrane     formation hydrodynamics     poly(ethylene-co-vinyl alcohol) copolymer    

Application of granular solid hydrodynamics to a well-graded unbound granular material undergoing triaxial

Shixiong SONG, Qicheng SUN, Feng JIN, Chuhan ZHANG

《结构与土木工程前沿(英文)》 2013年 第7卷 第1期   页码 83-88 doi: 10.1007/s11709-012-0148-8

摘要: Unbound granular materials (UGMs) are widely used as a base or a subbase in pavement construction. They are generally well graded and exhibit a higher peak strength than that of conventional cohesionless granular materials. By using a simplified version of granular solid hydrodynamics (GSH), a set of GSH material constants is determined for a UGM material. The deviatoric stress and volumetric strain caused by triaxial compression are calculated and then compared with experimental data. The results indicate that the GSH theory is able to describe such a special type of granular materials.

关键词: granular solid hydrodynamics     unbound granular material (UGM)     triaxial tests    

Nano thermo-hydrodynamics method for investigating cell membrane fluidity

YANG Yang, LIU Jing

《能源前沿(英文)》 2008年 第2卷 第2期   页码 121-128 doi: 10.1007/s11708-008-0033-2

摘要: As a barrier to compartmentalize cells, membranes form the interface between a cell and its surroundings. The essential function of a membrane is to maintain a relatively stable environment in the cell, exchange substances selectively and transfer energy and information continually from the outside. It is intriguing that above the phase transition temperature, the membrane lipid molecule will have three modes–lateral diffusion, rotational movement and flip-flop activity. These thermodynamic processes are vital to cell existence, growth, division, differentiation and are also responsible for hundreds of thousands of phenomena in life. Previously, species transport across the membrane was interpreted mainly from a phenomenological view using a lumped system model. Therefore, detailed flow processes occurred in the membrane domain and clues related to life mechanism were not sufficiently tackled. Such important issues can be clarified by modeling nano scale thermal hydrodynamics over the gap space of a cell membrane. Previously observed complex membrane behaviors will be shown in this paper and explained by the thermally induced fluidic convections inside the membrane. A correlation between nano scale hydrodynamics, non-equilibrium thermodynamics and cell membrane activities is set up. The disclosed mechanisms are expected to provide a new viewpoint on the interaction between intracellular and extracellular processes through the membrane.

关键词: responsible     phenomenological     phenomena     modes–lateral diffusion     differentiation    

Alluvial channel hydrodynamics around tandem piers with downward seepage

Rutuja CHAVAN, Wenxin HUAI, Bimlesh KUMAR

《结构与土木工程前沿(英文)》 2020年 第14卷 第6期   页码 1445-1461 doi: 10.1007/s11709-020-0648-x

摘要: In this paper, we report the turbulent flow structures and the scour geometry around two piers with different diameters. An experiment was conducted on a non-uniform sand bed with two types of tandem arrangements, namely, pier (T1) with a 75 mm front and 90 mm rear, and pier (T2) with a 90 mm front and 75 mm rear, with and without-seepage flows, respectively. A strong wake region was observed behind the piers, but the vortex strength diminished with downward seepage. Streamwise velocity was found to be maximum near the bed downstream of the piers and at the edge of the scour hole upstream of the piers. Quadrant analysis was used to recognize the susceptible region for sediment entrainment and deposition. Upstream of the piers near the bed, the moments, turbulent kinetic energy (TKE), and TKE fluxes were found to decrease with downward seepage, in contrast to those in a plane mobile bed without piers. The reduction percentages of scour depth at the rear pier compared with the front one were approximately 40% for T1 and 60% for T2. Downward seepage also resulted in restrained growth of scouring with time.

关键词: scour     seepage     Strouhal number     tandem arrangement     turbulent characteristics    

High velocity impact of metal sphere on thin metallic plate using smooth particle hydrodynamics (SPH)

Hossein ASADI KALAMEH, Arash KARAMALI, Cosmin ANITESCU, Timon RABCZUK

《结构与土木工程前沿(英文)》 2012年 第6卷 第2期   页码 101-110 doi: 10.1007/s11709-012-0160-z

摘要: The modeling of high velocity impact is an important topic in impact engineering. Due to various constraints, experimental data are extremely limited. Therefore, detailed numerical simulation can be considered as a desirable alternative. However, the physical processes involved in the impact are very sophisticated; hence a practical and complete reproduction of the phenomena involves complicated numerical models. In this paper, we present a smoothed particle hydrodynamics (SPH) method to model two-dimensional impact of metal sphere on thin metallic plate. The simulations are applied to different materials (Aluminum, Lead and Steel); however the target and projectile are formed of similar metals. A wide range of velocities (300, 1000, 2000, and 3100 m/s) are considered in this study. The goal is to study the most sensitive input parameters (impact velocity and plate thickness) on the longitudinal extension of the projectile, penetration depth and damage crater.

关键词: smoothed particle hydrodynamics     high velocity impact     sensitivity analysis    

Unconventional hydrodynamics of hybrid fluid made of liquid metals and aqueous solution under applied

Xu-Dong ZHANG, Yue SUN, Sen CHEN, Jing LIU

《能源前沿(英文)》 2018年 第12卷 第2期   页码 276-296 doi: 10.1007/s11708-018-0545-3

摘要: The hydrodynamic characteristics of hybrid fluid made of liquid metal/aqueous solution are elementary in the design and operation of conductive flow in a variety of newly emerging areas such as chip cooling, soft robot, and biomedical practices. In terms of physical and chemical properties, such as density, thermal conductivity and electrical conductivity, their huge differences between the two fluidic phases remain a big challenge for analyzing the hybrid flow behaviors. Besides, the liquid metal immersed in the solution can move and deform when administrated with non-contact electromagnetic force, or even induced by redox reaction, which is entirely different from the cases of conventional contact force. Owing to its remarkable capability in flow and deformation, liquid metal immersed in the solution is apt to deform on an extremely large scale, resulting in marked changes on its boundary and interface. However, the working mecha- nisms of the movement and deformation of liquid metal lack appropriate models to describe such scientific issues via a set of well-established unified equations. To promote investigations in this important area, the present paper is dedicated to summarizing this unconventional hydrodynamics from experiment, theory, and simulation. Typical experimental phenomena and basic working mechanisms are illustrated, followed by the movement and deformation theories to explain these phenomena. Several representative simulation methods are then proposed to tackle the governing functions of the electrohydrodynamics. Finally, prospects and challenges are raised, offering an insight into the new physics of the hybrid fluid under applied fields.

关键词: liquid metal     hybrid fluid     hydrodynamics     surface tension     applied fields     self-actuation    

CFD simulation of the hydrodynamics in an internal air-lift reactor with two different configurations

Mona EBRAHIMIFAKHAR, Elmira MOHSENZADEH, Sadegh MORADI, Mostafa MORAVEJI, Mahmoud SALIMI

《化学科学与工程前沿(英文)》 2011年 第5卷 第4期   页码 455-462 doi: 10.1007/s11705-011-1116-x

摘要: Computational fluid dynamics (CFD) was used to investigate the hydrodynamic parameters of two internal airlift bioreactors with different configurations. Both had a riser diameter of 0.1 m. The model was used to predict the effect of the reactor geometry on the reactor hydrodynamics. Water was utilized as the continuous phase and air in the form of bubbles was applied as the dispersed phase. A two-phase flow model provided by the bubbly flow application mode was employed in this project. In the liquid phase, the turbulence can be described using the - model. Simulated gas holdup and liquid circulation velocity results were compared with experimental data. The predictions of the simulation are in good agreement with the experimental data.

关键词: airlift reactor     gas holdup     liquid circulation velocity     bubbly flow     computational fluid dynamics (CFD)    

Application of a weakly compressible smoothed particle hydrodynamics multi-phase model to non-cohesive

Rasoul MEMARZADEH, Gholamabbas BARANI, Mahnaz GHAEINI-HESSAROEYEH

《结构与土木工程前沿(英文)》 2018年 第12卷 第3期   页码 412-424 doi: 10.1007/s11709-017-0432-8

摘要:

The subject of present study is the application of mesh free Lagrangian two-dimensional non-cohesive sediment transport model applied to a two-phase flow over an initially trapezoidal-shaped sediment embankment. The governing equations of the present model are the Navier-Stocks equations solved using Weakly Compressible Smoothed Particle Hydrodynamics (WCSPH) method. To simulate the movement of sediment particles, the model considers a powerful two-part technique; when the sediment phase has rigid behavior, only the force term due to shear stress in the Navier-Stokes equations is used for simulation of sediment particles’ movement. Otherwise, all the Navier-Stokes force terms are used for transport simulation of sediment particles. In the present model, the interactions between different phases are calculated automatically, even with considerable difference between the density and viscosity of phases. Validation of the model is performed using simulation of available laboratory experiments, and the comparison between computational results and experimental data shows that the model generally predicts well the flow propagation over movable beds, the induced sediment transport and bed changes, and temporal evolution of embankment breaching.

关键词: WCSPH method     non-cohesive sediment transport     rheological model     two-part technique     two-phase dam break    

Time-varying formation tracking for uncertain second-order nonlinearmulti-agent systems

Mao-peng RAN, Li-hua XIE, Jun-cheng LI

《信息与电子工程前沿(英文)》 2019年 第20卷 第1期   页码 76-87 doi: 10.1631/FITEE.1800557

摘要:

Our study is concerned with the time-varying formation tracking problem for second-order multi-agent systems that are subject to unknown nonlinear dynamics and external disturbance, and the states of the followers form a predefined time-varying formation while tracking the state of the leader. The total uncertainty lumps the unknown nonlinear dynamics and the external disturbance, and is regarded as an extended state of the agent. To estimate the total uncertainty, we design an extended state observer (ESO). Then we propose a novel ESO based time-varying formation tracking protocol. It is proved that, under the proposed protocol, the ESO estimation error and the time-varying formation tracking error can be made arbitrarily small. An application to the target enclosing problem for multiple unmanned aerial vehicles (UAVs) verifies the effectiveness and superiority of the proposed approach.

关键词: Multi-agent system     Time-varying formation     Formation tracking     Nonlinear dynamics     Extended state observer (ESO)    

3D finite element prediction of chip flow, burr formation, and cutting forces in micro end-milling of

A. DAVOUDINEJAD, P. PARENTI, M. ANNONI

《机械工程前沿(英文)》 2017年 第12卷 第2期   页码 203-214 doi: 10.1007/s11465-017-0421-6

摘要:

Predictive models for machining operations have been significantly improved through numerous methods in recent decades. This study proposed a 3D finite element modeling (3D FEM) approach for the micro end-milling of Al6061-T6. Finite element (FE) simulations were performed under different cutting conditions to obtain realistic numerical predictions of chip flow, burr formation, and cutting forces. FE modeling displayed notable advantages, such as capability to easily handle any type of tool geometry and any side effect on chip formation, including thermal aspect and material property changes. The proposed 3D FE model considers the effects of mill helix angle and cutting edge radius on the chip. The prediction capability of the FE model was validated by comparing numerical model and experimental test results. Burr dimension trends were correlated with force profile shapes. However, the FE predictions overestimated the real force magnitude. This overestimation indicates that the model requires further development.

关键词: 3D finite element modeling     micro end-milling     cutting force     chip formation     burr formation    

Mechanistic insight into the biofilm formation and process performance of a passive aeration ditch (PAD

《环境科学与工程前沿(英文)》 2022年 第16卷 第7期 doi: 10.1007/s11783-021-1494-3

摘要:

• A Passive Aeration Ditch was developed to treat decentralized wastewater.

关键词: Decentralized wastewater     Passive aeration ditch     Biofilm formation     C/N ratio     Salinity     Model simulation    

Is atmospheric oxidation capacity better in indicating tropospheric O formation?

《环境科学与工程前沿(英文)》 2022年 第16卷 第5期 doi: 10.1007/s11783-022-1544-5

摘要:

● This study summarizes and evaluates different approaches that indicate O3 formation.

关键词: O3     AOC     O3 formation regime    

Formation mechanism and modeling of surface waviness in incremental sheet forming

《机械工程前沿(英文)》 2022年 第17卷 第2期 doi: 10.1007/s11465-022-0679-1

摘要: Improving and controlling surface quality has always been a challenge for incremental sheet forming (ISF), whereas the generation mechanism of waviness surface is still unknown, which impedes the widely application of ISF in the industrial field. In this paper, the formation mechanism and the prediction of waviness are both investigated through experiments, numerical simulation, and theoretical analysis. Based on a verified finite element model, the waviness topography is predicted numerically for the first time, and its generation is attributed to the residual bending deformation through deformation history analysis. For more efficient engineering application, a theoretical model for waviness height is proposed based on the generation mechanism, using a modified strain function considering deformation modes. This work is favorable for the perfection of formation mechanism and control of surface quality in ISF.

关键词: surface waviness     incremental sheet forming     numerical simulation     formation mechanism     deformation history    

New insights into the formation of ammonium nitrate from a physical and chemical level perspective

《环境科学与工程前沿(英文)》 2023年 第17卷 第11期 doi: 10.1007/s11783-023-1737-6

摘要:

● Factor analysis of ammonium nitrate formation based on thermodynamic theory.

关键词: Ammonium nitrate formation     Thermodynamic theory     Aerosol liquid water content     Source apportionment    

High-precision standard enthalpy of formation for polycyclic aromatic hydrocarbons predicting from general

《化学科学与工程前沿(英文)》 2022年 第16卷 第12期   页码 1743-1750 doi: 10.1007/s11705-022-2184-9

摘要: The standard enthalpy of formation is an important predictor of the reaction heat of a chemical reaction. In this work, a high-precision method was developed to calculate accurate standard enthalpies of formation for polycyclic aromatic hydrocarbons based on the general connectivity based hierarchy (CBH) with the discrete correction of atomization energy. Through a comparison with available experimental findings and other high-precision computational results, it was found that the present method can give a good description of enthalpy of formation for polycyclic aromatic hydrocarbons. Since CBH schemes can broaden the scope of application, this method can be used to investigate the energetic properties of larger polycyclic aromatic hydrocarbons to achieve a high-precision calculation at the CCSD(T)/CBS level. In addition, the energetic properties of CBH fragments can be accurately calculated and integrated into a database for future use, which will increase computational efficiency. We hope this work can give new insights into the energetic properties of larger systems.

关键词: standard enthalpy of formation     polycyclic aromatic hydrocarbons     connectivity based hierarchy     high-precision calculation    

标题 作者 时间 类型 操作

, antifouling, and permeation properties of polysulfone ultrafiltration membrane: thermodynamic and formation

期刊论文

Application of granular solid hydrodynamics to a well-graded unbound granular material undergoing triaxial

Shixiong SONG, Qicheng SUN, Feng JIN, Chuhan ZHANG

期刊论文

Nano thermo-hydrodynamics method for investigating cell membrane fluidity

YANG Yang, LIU Jing

期刊论文

Alluvial channel hydrodynamics around tandem piers with downward seepage

Rutuja CHAVAN, Wenxin HUAI, Bimlesh KUMAR

期刊论文

High velocity impact of metal sphere on thin metallic plate using smooth particle hydrodynamics (SPH)

Hossein ASADI KALAMEH, Arash KARAMALI, Cosmin ANITESCU, Timon RABCZUK

期刊论文

Unconventional hydrodynamics of hybrid fluid made of liquid metals and aqueous solution under applied

Xu-Dong ZHANG, Yue SUN, Sen CHEN, Jing LIU

期刊论文

CFD simulation of the hydrodynamics in an internal air-lift reactor with two different configurations

Mona EBRAHIMIFAKHAR, Elmira MOHSENZADEH, Sadegh MORADI, Mostafa MORAVEJI, Mahmoud SALIMI

期刊论文

Application of a weakly compressible smoothed particle hydrodynamics multi-phase model to non-cohesive

Rasoul MEMARZADEH, Gholamabbas BARANI, Mahnaz GHAEINI-HESSAROEYEH

期刊论文

Time-varying formation tracking for uncertain second-order nonlinearmulti-agent systems

Mao-peng RAN, Li-hua XIE, Jun-cheng LI

期刊论文

3D finite element prediction of chip flow, burr formation, and cutting forces in micro end-milling of

A. DAVOUDINEJAD, P. PARENTI, M. ANNONI

期刊论文

Mechanistic insight into the biofilm formation and process performance of a passive aeration ditch (PAD

期刊论文

Is atmospheric oxidation capacity better in indicating tropospheric O formation?

期刊论文

Formation mechanism and modeling of surface waviness in incremental sheet forming

期刊论文

New insights into the formation of ammonium nitrate from a physical and chemical level perspective

期刊论文

High-precision standard enthalpy of formation for polycyclic aromatic hydrocarbons predicting from general

期刊论文